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Investigating the Effect of ZnSe (ETM) and Cu2O (HTM) on Absorber Layer on the Performance of Pervoskite Solar Cell Using SCAPS-1D

Received: 19 December 2019     Accepted: 6 February 2020     Published: 17 March 2020
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Abstract

Tin perovskite (CH3NH3SnI3) have attracted a lot of attention and could be a viable alternative material to replace lead perovskite in thin film solar cells. A detailed understanding on the effects of each component of a solar cell on its output performance is needed to further develop the technology. In this work, a numerical simulation of a planar hetero-junction tin based perovskite solar cell using Solar Cell Capacitance Simulator (SCAPS) to study some parameters that can influence the performance of tin PSC with Cu2O as HTL and ZnSe as ETL performed. The thickness of absorber material, ETL and HTL, the bandgap of absorber material and ETL was investigated. Results revealed that the thickness and bandgap of the absorber material and ETL of ZnSe strongly influence the PCE of the device. The performance of the cell increases with reduction in thickness of ZnSe. ZnSe is found to be a replacement for TiO2 which is expensive. Cuprous oxide of HTL in tin based PSC is efficient and better than the expensive spiro-MeOTAD which is easily degradable. Furthermore, results of simulation and optimization of various thicknesses indicates that ZnSe has a PCE of 21.11%, FF of 68.33%, JSC of 33.51mA/cm2 and VOC of 0.92V. These values slightly increase after optimization of parameters to PCE of 22.28%, FF of 70.94%, JSC of 31.01mA/cm2 and VOC of 1.01V.

Published in American Journal of Physics and Applications (Volume 8, Issue 1)
DOI 10.11648/j.ajpa.20200801.12
Page(s) 8-18
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Solar Cell, Perovskite, Device Simulation, SCAPS, Efficiency

References
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    Joshua Adeyemi Owolabi, Mohammed Yusuf Onimisi, Jessica Amuchi Ukwenya, Alexander Bulus Bature, Ugbe Raphael Ushiekpan. (2020). Investigating the Effect of ZnSe (ETM) and Cu2O (HTM) on Absorber Layer on the Performance of Pervoskite Solar Cell Using SCAPS-1D. American Journal of Physics and Applications, 8(1), 8-18. https://doi.org/10.11648/j.ajpa.20200801.12

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    ACS Style

    Joshua Adeyemi Owolabi; Mohammed Yusuf Onimisi; Jessica Amuchi Ukwenya; Alexander Bulus Bature; Ugbe Raphael Ushiekpan. Investigating the Effect of ZnSe (ETM) and Cu2O (HTM) on Absorber Layer on the Performance of Pervoskite Solar Cell Using SCAPS-1D. Am. J. Phys. Appl. 2020, 8(1), 8-18. doi: 10.11648/j.ajpa.20200801.12

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    AMA Style

    Joshua Adeyemi Owolabi, Mohammed Yusuf Onimisi, Jessica Amuchi Ukwenya, Alexander Bulus Bature, Ugbe Raphael Ushiekpan. Investigating the Effect of ZnSe (ETM) and Cu2O (HTM) on Absorber Layer on the Performance of Pervoskite Solar Cell Using SCAPS-1D. Am J Phys Appl. 2020;8(1):8-18. doi: 10.11648/j.ajpa.20200801.12

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  • @article{10.11648/j.ajpa.20200801.12,
      author = {Joshua Adeyemi Owolabi and Mohammed Yusuf Onimisi and Jessica Amuchi Ukwenya and Alexander Bulus Bature and Ugbe Raphael Ushiekpan},
      title = {Investigating the Effect of ZnSe (ETM) and Cu2O (HTM) on Absorber Layer on the Performance of Pervoskite Solar Cell Using SCAPS-1D},
      journal = {American Journal of Physics and Applications},
      volume = {8},
      number = {1},
      pages = {8-18},
      doi = {10.11648/j.ajpa.20200801.12},
      url = {https://doi.org/10.11648/j.ajpa.20200801.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpa.20200801.12},
      abstract = {Tin perovskite (CH3NH3SnI3) have attracted a lot of attention and could be a viable alternative material to replace lead perovskite in thin film solar cells. A detailed understanding on the effects of each component of a solar cell on its output performance is needed to further develop the technology. In this work, a numerical simulation of a planar hetero-junction tin based perovskite solar cell using Solar Cell Capacitance Simulator (SCAPS) to study some parameters that can influence the performance of tin PSC with Cu2O as HTL and ZnSe as ETL performed. The thickness of absorber material, ETL and HTL, the bandgap of absorber material and ETL was investigated. Results revealed that the thickness and bandgap of the absorber material and ETL of ZnSe strongly influence the PCE of the device. The performance of the cell increases with reduction in thickness of ZnSe. ZnSe is found to be a replacement for TiO2 which is expensive. Cuprous oxide of HTL in tin based PSC is efficient and better than the expensive spiro-MeOTAD which is easily degradable. Furthermore, results of simulation and optimization of various thicknesses indicates that ZnSe has a PCE of 21.11%, FF of 68.33%, JSC of 33.51mA/cm2 and VOC of 0.92V. These values slightly increase after optimization of parameters to PCE of 22.28%, FF of 70.94%, JSC of 31.01mA/cm2 and VOC of 1.01V.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Investigating the Effect of ZnSe (ETM) and Cu2O (HTM) on Absorber Layer on the Performance of Pervoskite Solar Cell Using SCAPS-1D
    AU  - Joshua Adeyemi Owolabi
    AU  - Mohammed Yusuf Onimisi
    AU  - Jessica Amuchi Ukwenya
    AU  - Alexander Bulus Bature
    AU  - Ugbe Raphael Ushiekpan
    Y1  - 2020/03/17
    PY  - 2020
    N1  - https://doi.org/10.11648/j.ajpa.20200801.12
    DO  - 10.11648/j.ajpa.20200801.12
    T2  - American Journal of Physics and Applications
    JF  - American Journal of Physics and Applications
    JO  - American Journal of Physics and Applications
    SP  - 8
    EP  - 18
    PB  - Science Publishing Group
    SN  - 2330-4308
    UR  - https://doi.org/10.11648/j.ajpa.20200801.12
    AB  - Tin perovskite (CH3NH3SnI3) have attracted a lot of attention and could be a viable alternative material to replace lead perovskite in thin film solar cells. A detailed understanding on the effects of each component of a solar cell on its output performance is needed to further develop the technology. In this work, a numerical simulation of a planar hetero-junction tin based perovskite solar cell using Solar Cell Capacitance Simulator (SCAPS) to study some parameters that can influence the performance of tin PSC with Cu2O as HTL and ZnSe as ETL performed. The thickness of absorber material, ETL and HTL, the bandgap of absorber material and ETL was investigated. Results revealed that the thickness and bandgap of the absorber material and ETL of ZnSe strongly influence the PCE of the device. The performance of the cell increases with reduction in thickness of ZnSe. ZnSe is found to be a replacement for TiO2 which is expensive. Cuprous oxide of HTL in tin based PSC is efficient and better than the expensive spiro-MeOTAD which is easily degradable. Furthermore, results of simulation and optimization of various thicknesses indicates that ZnSe has a PCE of 21.11%, FF of 68.33%, JSC of 33.51mA/cm2 and VOC of 0.92V. These values slightly increase after optimization of parameters to PCE of 22.28%, FF of 70.94%, JSC of 31.01mA/cm2 and VOC of 1.01V.
    VL  - 8
    IS  - 1
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Author Information
  • Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria

  • Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria

  • Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria

  • Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria

  • Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria

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