Use of Carbonaceous Materials Derived from Co-products of <i>Lophira lanceolata</i> for Adsorption Tests of Congo Red Dye

Elie Sogbochi; Pierre Girods; Guevara Nonviho; Sebastien Fontana; Yann Rogaume; Dominique Codjo Koko Sohounhloue

doi:doi:10.11648/j.ajpc.20221104.12

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Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye

Elie Sogbochi, Pierre Girods, Guevara Nonviho, Sebastien Fontana, Yann Rogaume, Dominique Codjo Koko Sohounhloue

Published in American Journal of Physical Chemistry (Volume 11, Issue 4)

Received: 7 September 2022 Accepted: 29 September 2022 Published: 24 October 2022

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Abstract

The present study aims to valorize the hulls of Lophira lanceolata, an agricultural by-product in Benin. This natural resource, which is abundant in tropical countries, including Benin, has so far been considered as a biodegradable waste and treated as such. However, it has adsorption properties that can be exploited by transforming it into activated carbon for various uses, including water purification. For this purpose, activated carbons have been developed from the said hulls chemically impregnated with phosphoric acid. The adsorption kinetics of red Congo on these activated carbons is governed by the pseudo-second order kinetic model. The adsorption isotherms of Congo red by the Langmuir model give adsorbed quantities varying between 1250 and 1666.67 mg.g^-1, but this model is not credible to explain the mechanism. The Freundlich model is the most credible to explain the Congo red adsorption phenomenon. It indicates the cooperative and multilayer adsorption of Congo red on activated carbons. The thermodynamic study of the Congo red adsorption process shows that it is exothermic, spontaneous, and the Congo red molecules fixed are ordered on the surface of the activated carbons. Thus, it should be noted that the adsorbents produced can be used for the removal of anionic dyes in aqueous solution and effective at low concentrations.

Published in	American Journal of Physical Chemistry (Volume 11, Issue 4)
DOI	10.11648/j.ajpc.20221104.12
Page(s)	91-101
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Lophira lanceolata, Biomass, Activated Carbon, Red Congo, Adsorption

References

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APA Style

Elie Sogbochi, Pierre Girods, Guevara Nonviho, Sebastien Fontana, Yann Rogaume, et al. (2022). Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye. American Journal of Physical Chemistry, 11(4), 91-101. https://doi.org/10.11648/j.ajpc.20221104.12

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ACS Style

Elie Sogbochi; Pierre Girods; Guevara Nonviho; Sebastien Fontana; Yann Rogaume, et al. Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye. Am. J. Phys. Chem. 2022, 11(4), 91-101. doi: 10.11648/j.ajpc.20221104.12

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AMA Style

Elie Sogbochi, Pierre Girods, Guevara Nonviho, Sebastien Fontana, Yann Rogaume, et al. Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye. Am J Phys Chem. 2022;11(4):91-101. doi: 10.11648/j.ajpc.20221104.12

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@article{10.11648/j.ajpc.20221104.12,
  author = {Elie Sogbochi and Pierre Girods and Guevara Nonviho and Sebastien Fontana and Yann Rogaume and Dominique Codjo Koko Sohounhloue},
  title = {Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye},
  journal = {American Journal of Physical Chemistry},
  volume = {11},
  number = {4},
  pages = {91-101},
  doi = {10.11648/j.ajpc.20221104.12},
  url = {https://doi.org/10.11648/j.ajpc.20221104.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20221104.12},
  abstract = {The present study aims to valorize the hulls of Lophira lanceolata, an agricultural by-product in Benin. This natural resource, which is abundant in tropical countries, including Benin, has so far been considered as a biodegradable waste and treated as such. However, it has adsorption properties that can be exploited by transforming it into activated carbon for various uses, including water purification. For this purpose, activated carbons have been developed from the said hulls chemically impregnated with phosphoric acid. The adsorption kinetics of red Congo on these activated carbons is governed by the pseudo-second order kinetic model. The adsorption isotherms of Congo red by the Langmuir model give adsorbed quantities varying between 1250 and 1666.67 mg.g-1, but this model is not credible to explain the mechanism. The Freundlich model is the most credible to explain the Congo red adsorption phenomenon. It indicates the cooperative and multilayer adsorption of Congo red on activated carbons. The thermodynamic study of the Congo red adsorption process shows that it is exothermic, spontaneous, and the Congo red molecules fixed are ordered on the surface of the activated carbons. Thus, it should be noted that the adsorbents produced can be used for the removal of anionic dyes in aqueous solution and effective at low concentrations.},
 year = {2022}
}

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TY  - JOUR
T1  - Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye
AU  - Elie Sogbochi
AU  - Pierre Girods
AU  - Guevara Nonviho
AU  - Sebastien Fontana
AU  - Yann Rogaume
AU  - Dominique Codjo Koko Sohounhloue
Y1  - 2022/10/24
PY  - 2022
N1  - https://doi.org/10.11648/j.ajpc.20221104.12
DO  - 10.11648/j.ajpc.20221104.12
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 91
EP  - 101
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20221104.12
AB  - The present study aims to valorize the hulls of Lophira lanceolata, an agricultural by-product in Benin. This natural resource, which is abundant in tropical countries, including Benin, has so far been considered as a biodegradable waste and treated as such. However, it has adsorption properties that can be exploited by transforming it into activated carbon for various uses, including water purification. For this purpose, activated carbons have been developed from the said hulls chemically impregnated with phosphoric acid. The adsorption kinetics of red Congo on these activated carbons is governed by the pseudo-second order kinetic model. The adsorption isotherms of Congo red by the Langmuir model give adsorbed quantities varying between 1250 and 1666.67 mg.g-1, but this model is not credible to explain the mechanism. The Freundlich model is the most credible to explain the Congo red adsorption phenomenon. It indicates the cooperative and multilayer adsorption of Congo red on activated carbons. The thermodynamic study of the Congo red adsorption process shows that it is exothermic, spontaneous, and the Congo red molecules fixed are ordered on the surface of the activated carbons. Thus, it should be noted that the adsorbents produced can be used for the removal of anionic dyes in aqueous solution and effective at low concentrations.
VL  - 11
IS  - 4
ER  -

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Author Information

Elie Sogbochi

Laboratory of Study and Research in Applied Chemistry, University of Abomey-Calavi, Cotonou, Benin
Pierre Girods

Laboratory of Study and Research on Wood Materials, University of Lorraine, Epinal, France
Guevara Nonviho

Laboratory of Study and Research in Applied Chemistry, University of Abomey-Calavi, Cotonou, Benin
Sebastien Fontana

Jean Lamour Institute, Joint Research Unit 7198 National Scientific Research Centre, University of Lorraine, Nancy, France
Yann Rogaume

Laboratory of Study and Research on Wood Materials, University of Lorraine, Epinal, France
Dominique Codjo Koko Sohounhloue

Laboratory of Study and Research in Applied Chemistry, University of Abomey-Calavi, Cotonou, Benin

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APA Style

Elie Sogbochi, Pierre Girods, Guevara Nonviho, Sebastien Fontana, Yann Rogaume, et al. (2022). Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye. American Journal of Physical Chemistry, 11(4), 91-101. https://doi.org/10.11648/j.ajpc.20221104.12

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ACS Style

Elie Sogbochi; Pierre Girods; Guevara Nonviho; Sebastien Fontana; Yann Rogaume, et al. Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye. Am. J. Phys. Chem. 2022, 11(4), 91-101. doi: 10.11648/j.ajpc.20221104.12

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AMA Style

Elie Sogbochi, Pierre Girods, Guevara Nonviho, Sebastien Fontana, Yann Rogaume, et al. Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye. Am J Phys Chem. 2022;11(4):91-101. doi: 10.11648/j.ajpc.20221104.12

Copy | Download

@article{10.11648/j.ajpc.20221104.12,
  author = {Elie Sogbochi and Pierre Girods and Guevara Nonviho and Sebastien Fontana and Yann Rogaume and Dominique Codjo Koko Sohounhloue},
  title = {Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye},
  journal = {American Journal of Physical Chemistry},
  volume = {11},
  number = {4},
  pages = {91-101},
  doi = {10.11648/j.ajpc.20221104.12},
  url = {https://doi.org/10.11648/j.ajpc.20221104.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20221104.12},
  abstract = {The present study aims to valorize the hulls of Lophira lanceolata, an agricultural by-product in Benin. This natural resource, which is abundant in tropical countries, including Benin, has so far been considered as a biodegradable waste and treated as such. However, it has adsorption properties that can be exploited by transforming it into activated carbon for various uses, including water purification. For this purpose, activated carbons have been developed from the said hulls chemically impregnated with phosphoric acid. The adsorption kinetics of red Congo on these activated carbons is governed by the pseudo-second order kinetic model. The adsorption isotherms of Congo red by the Langmuir model give adsorbed quantities varying between 1250 and 1666.67 mg.g-1, but this model is not credible to explain the mechanism. The Freundlich model is the most credible to explain the Congo red adsorption phenomenon. It indicates the cooperative and multilayer adsorption of Congo red on activated carbons. The thermodynamic study of the Congo red adsorption process shows that it is exothermic, spontaneous, and the Congo red molecules fixed are ordered on the surface of the activated carbons. Thus, it should be noted that the adsorbents produced can be used for the removal of anionic dyes in aqueous solution and effective at low concentrations.},
 year = {2022}
}

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TY  - JOUR
T1  - Use of Carbonaceous Materials Derived from Co-products of Lophira lanceolata for Adsorption Tests of Congo Red Dye
AU  - Elie Sogbochi
AU  - Pierre Girods
AU  - Guevara Nonviho
AU  - Sebastien Fontana
AU  - Yann Rogaume
AU  - Dominique Codjo Koko Sohounhloue
Y1  - 2022/10/24
PY  - 2022
N1  - https://doi.org/10.11648/j.ajpc.20221104.12
DO  - 10.11648/j.ajpc.20221104.12
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 91
EP  - 101
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20221104.12
AB  - The present study aims to valorize the hulls of Lophira lanceolata, an agricultural by-product in Benin. This natural resource, which is abundant in tropical countries, including Benin, has so far been considered as a biodegradable waste and treated as such. However, it has adsorption properties that can be exploited by transforming it into activated carbon for various uses, including water purification. For this purpose, activated carbons have been developed from the said hulls chemically impregnated with phosphoric acid. The adsorption kinetics of red Congo on these activated carbons is governed by the pseudo-second order kinetic model. The adsorption isotherms of Congo red by the Langmuir model give adsorbed quantities varying between 1250 and 1666.67 mg.g-1, but this model is not credible to explain the mechanism. The Freundlich model is the most credible to explain the Congo red adsorption phenomenon. It indicates the cooperative and multilayer adsorption of Congo red on activated carbons. The thermodynamic study of the Congo red adsorption process shows that it is exothermic, spontaneous, and the Congo red molecules fixed are ordered on the surface of the activated carbons. Thus, it should be noted that the adsorbents produced can be used for the removal of anionic dyes in aqueous solution and effective at low concentrations.
VL  - 11
IS  - 4
ER  -

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