Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye

Zhiyong Han; Dehua Wang; Jie Wu; Qingyue Xiong; Yanxia Zhang; Kaiqing Zhang

doi:doi:10.11648/j.am.20211004.14

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Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye

Zhiyong Han, Dehua Wang, Jie Wu, Qingyue Xiong, Yanxia Zhang, Kaiqing Zhang

Published in Advances in Materials (Volume 10, Issue 4)

Received: 25 December 2021 Published: 29 December 2021

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Abstract

The agricultural and forestry waste pine needle was selected to prepare the biochar which magnetized by the Fe₃O₄ to treat the typical wastewaters of the dye methylene blue (MB) and carmine (P4R) in view of the problem of quick increasing dye wastewater caused by the rapid development of textile, printing and dyeing industries, and the research result showed the experimental values of the maximum adsorption capacity of modified biochar for MB and P4R were 465.6mg·g^-1 and 336.6mg·g^-1 respectively. When the dosage of MBC is 0.010g and 0.015g, both the removal rate and the adsorption capacity can be maintained at a high level. Lower pH is conducive to the adsorption of P4R, and a higher pH is conducive to the adsorption of MB. As the adsorption time and initial dye concentration increase, the adsorption capacity of both dyes increases. As the temperature increases, the amount of MB adsorption increases, while the amount of P4R adsorption decreases and the adsorption of MB by MBC is a high-temperature spontaneous adsorption process, and the adsorption of P4R is a low-temperature spontaneous adsorption. The Langmuir model can better describe the adsorption process of MBC to MB, which is a single-layer adsorption, and the Freundlich adsorption model can better describe the adsorption process of MBC to P4R, which is a multi-layer adsorption. The adsorption of MB and P4R by MBC conforms to the quasi-second-order kinetic model.

Published in	Advances in Materials (Volume 10, Issue 4)
DOI	10.11648/j.am.20211004.14
Page(s)	75-86
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Biochar, Dye Modification, Magnetism, Adsorption, Dye Wastewater, Pine Needle

References

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[3]	Sen, S. K., Raut. Fungal decolouration and degradation of azo dyes: A review [J]. Fungal biology reviews, 2016, 30 (3): 112-133.
[4]	Zhang, O’Connor, Wang, et al. A green biochar/iron oxide composite for methylene blue removal [J]. Journal of Hazardous Materials, 2020, 384.
[5]	An, Qiang, Zhao, et al. An alkali modified biochar for enhancing Mn²⁺ adsorption: Performance and chemical mechanism [J]. Materials Chemistry and Physics, 2020, 248.
[6]	Umran, Tezcan, Un, Oduncu, et al. Adsorption of Disperse Orange 30 dye onto activated carbon derived from Holm Oak (Quercus Ilex) acorns: A 3 (k) factorial design and analysis. [J]. Journal of Environmental Management, 2015, 155: 89-96.
[7]	Azargohar R, Dalai A K. Steam and KOH activation of biochar: Experimental and modeling studies [J]. Microporous & Mesoporous Materials, 2008, 110 (2-3): 413-421.
[8]	Mohammed J, Nasri N S, Zaini M, et al. Comparison on the Characteristics of Bio-Based Porous Carbons by Physical and Novel Chemical Activation [J]. Applied Mechanics and Materials, 2014, 554.
[9]	Tezcan, Un, U, Erginel N, et al. Adsorption of Disperse Orange 30 dye onto activated carbon derived from Holm Oak (Quercus Ilex) acorns: A 3k factorial design and analysis [J]. Journal of Environmental Management, 2015, 155: 89-96.
[10]	Trakal, Veselská, Šafařík. Lead and cadmium sorption mechanisms on magnetically modified biochars [J]. Bioresource technology, 2016, 203: 318-2.
[11]	Mohammad Ameera F., Mourad Aya A-H. I., Galiwango Emmanuel et al. Effective and sustainable adsorbent materials for oil spill cleanup based on a multistage desalination process [J] Journal of Environmental Management, 2021, 299.
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[13]	Lee Jae-In, Kim Jeong-Man, Yoo Soo-Cheul et al. Restoring phosphorus from water to soil: Using calcined eggshells for P adsorption and subsequent application of the adsorbent as a P fertilizer [J] Chemosphere, 2022, 287 (P3).
[14]	Kayranli Birol Mechanism of interaction and removal of zinc with lignocellulosic adsorbents, closing the cycle with a soil conditioner [J] Journal of King Saud University - Science, 2021, 33 (8).
[15]	Mei Yanglu, Xu Jin, Zhang Yin et al. Effect of Fe–N modification on the properties of biochars and their adsorption behavior on tetracycline removal from aqueous solution [J] Bioresource Technology, 2021, 325.
[16]	Chen Juan, Liu Shanshan, Ge Heyi et al. A hydrophobic bio-adsorbent synthesized by nanoparticle-modified graphene oxide coated corn straw pith for dye adsorption and photocatalytic degradation [J] Environmental Technology, 2020, 41 (27).

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APA Style

Zhiyong Han, Dehua Wang, Jie Wu, Qingyue Xiong, Yanxia Zhang, et al. (2021). Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye. Advances in Materials, 10(4), 75-86. https://doi.org/10.11648/j.am.20211004.14

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ACS Style

Zhiyong Han; Dehua Wang; Jie Wu; Qingyue Xiong; Yanxia Zhang, et al. Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye. Adv. Mater. 2021, 10(4), 75-86. doi: 10.11648/j.am.20211004.14

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AMA Style

Zhiyong Han, Dehua Wang, Jie Wu, Qingyue Xiong, Yanxia Zhang, et al. Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye. Adv Mater. 2021;10(4):75-86. doi: 10.11648/j.am.20211004.14

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@article{10.11648/j.am.20211004.14,
  author = {Zhiyong Han and Dehua Wang and Jie Wu and Qingyue Xiong and Yanxia Zhang and Kaiqing Zhang},
  title = {Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye},
  journal = {Advances in Materials},
  volume = {10},
  number = {4},
  pages = {75-86},
  doi = {10.11648/j.am.20211004.14},
  url = {https://doi.org/10.11648/j.am.20211004.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20211004.14},
  abstract = {The agricultural and forestry waste pine needle was selected to prepare the biochar which magnetized by the Fe3O4 to treat the typical wastewaters of the dye methylene blue (MB) and carmine (P4R) in view of the problem of quick increasing dye wastewater caused by the rapid development of textile, printing and dyeing industries, and the research result showed the experimental values of the maximum adsorption capacity of modified biochar for MB and P4R were 465.6mg·g-1 and 336.6mg·g-1 respectively. When the dosage of MBC is 0.010g and 0.015g, both the removal rate and the adsorption capacity can be maintained at a high level. Lower pH is conducive to the adsorption of P4R, and a higher pH is conducive to the adsorption of MB. As the adsorption time and initial dye concentration increase, the adsorption capacity of both dyes increases. As the temperature increases, the amount of MB adsorption increases, while the amount of P4R adsorption decreases and the adsorption of MB by MBC is a high-temperature spontaneous adsorption process, and the adsorption of P4R is a low-temperature spontaneous adsorption. The Langmuir model can better describe the adsorption process of MBC to MB, which is a single-layer adsorption, and the Freundlich adsorption model can better describe the adsorption process of MBC to P4R, which is a multi-layer adsorption. The adsorption of MB and P4R by MBC conforms to the quasi-second-order kinetic model.},
 year = {2021}
}

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TY  - JOUR
T1  - Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye
AU  - Zhiyong Han
AU  - Dehua Wang
AU  - Jie Wu
AU  - Qingyue Xiong
AU  - Yanxia Zhang
AU  - Kaiqing Zhang
Y1  - 2021/12/29
PY  - 2021
N1  - https://doi.org/10.11648/j.am.20211004.14
DO  - 10.11648/j.am.20211004.14
T2  - Advances in Materials
JF  - Advances in Materials
JO  - Advances in Materials
SP  - 75
EP  - 86
PB  - Science Publishing Group
SN  - 2327-252X
UR  - https://doi.org/10.11648/j.am.20211004.14
AB  - The agricultural and forestry waste pine needle was selected to prepare the biochar which magnetized by the Fe3O4 to treat the typical wastewaters of the dye methylene blue (MB) and carmine (P4R) in view of the problem of quick increasing dye wastewater caused by the rapid development of textile, printing and dyeing industries, and the research result showed the experimental values of the maximum adsorption capacity of modified biochar for MB and P4R were 465.6mg·g-1 and 336.6mg·g-1 respectively. When the dosage of MBC is 0.010g and 0.015g, both the removal rate and the adsorption capacity can be maintained at a high level. Lower pH is conducive to the adsorption of P4R, and a higher pH is conducive to the adsorption of MB. As the adsorption time and initial dye concentration increase, the adsorption capacity of both dyes increases. As the temperature increases, the amount of MB adsorption increases, while the amount of P4R adsorption decreases and the adsorption of MB by MBC is a high-temperature spontaneous adsorption process, and the adsorption of P4R is a low-temperature spontaneous adsorption. The Langmuir model can better describe the adsorption process of MBC to MB, which is a single-layer adsorption, and the Freundlich adsorption model can better describe the adsorption process of MBC to P4R, which is a multi-layer adsorption. The adsorption of MB and P4R by MBC conforms to the quasi-second-order kinetic model.
VL  - 10
IS  - 4
ER  -

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Author Information

Zhiyong Han

College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, China
Dehua Wang

College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, China
Jie Wu

College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, China
Qingyue Xiong

College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, China
Yanxia Zhang

College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, China
Kaiqing Zhang

College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, China

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APA Style

Zhiyong Han, Dehua Wang, Jie Wu, Qingyue Xiong, Yanxia Zhang, et al. (2021). Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye. Advances in Materials, 10(4), 75-86. https://doi.org/10.11648/j.am.20211004.14

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ACS Style

Zhiyong Han; Dehua Wang; Jie Wu; Qingyue Xiong; Yanxia Zhang, et al. Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye. Adv. Mater. 2021, 10(4), 75-86. doi: 10.11648/j.am.20211004.14

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AMA Style

Zhiyong Han, Dehua Wang, Jie Wu, Qingyue Xiong, Yanxia Zhang, et al. Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye. Adv Mater. 2021;10(4):75-86. doi: 10.11648/j.am.20211004.14

Copy | Download

@article{10.11648/j.am.20211004.14,
  author = {Zhiyong Han and Dehua Wang and Jie Wu and Qingyue Xiong and Yanxia Zhang and Kaiqing Zhang},
  title = {Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye},
  journal = {Advances in Materials},
  volume = {10},
  number = {4},
  pages = {75-86},
  doi = {10.11648/j.am.20211004.14},
  url = {https://doi.org/10.11648/j.am.20211004.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20211004.14},
  abstract = {The agricultural and forestry waste pine needle was selected to prepare the biochar which magnetized by the Fe3O4 to treat the typical wastewaters of the dye methylene blue (MB) and carmine (P4R) in view of the problem of quick increasing dye wastewater caused by the rapid development of textile, printing and dyeing industries, and the research result showed the experimental values of the maximum adsorption capacity of modified biochar for MB and P4R were 465.6mg·g-1 and 336.6mg·g-1 respectively. When the dosage of MBC is 0.010g and 0.015g, both the removal rate and the adsorption capacity can be maintained at a high level. Lower pH is conducive to the adsorption of P4R, and a higher pH is conducive to the adsorption of MB. As the adsorption time and initial dye concentration increase, the adsorption capacity of both dyes increases. As the temperature increases, the amount of MB adsorption increases, while the amount of P4R adsorption decreases and the adsorption of MB by MBC is a high-temperature spontaneous adsorption process, and the adsorption of P4R is a low-temperature spontaneous adsorption. The Langmuir model can better describe the adsorption process of MBC to MB, which is a single-layer adsorption, and the Freundlich adsorption model can better describe the adsorption process of MBC to P4R, which is a multi-layer adsorption. The adsorption of MB and P4R by MBC conforms to the quasi-second-order kinetic model.},
 year = {2021}
}

Copy | Download

TY  - JOUR
T1  - Study on the Preparation of Magnetic Pine Needle Biochar and Its Adsorption Performance for the Dye
AU  - Zhiyong Han
AU  - Dehua Wang
AU  - Jie Wu
AU  - Qingyue Xiong
AU  - Yanxia Zhang
AU  - Kaiqing Zhang
Y1  - 2021/12/29
PY  - 2021
N1  - https://doi.org/10.11648/j.am.20211004.14
DO  - 10.11648/j.am.20211004.14
T2  - Advances in Materials
JF  - Advances in Materials
JO  - Advances in Materials
SP  - 75
EP  - 86
PB  - Science Publishing Group
SN  - 2327-252X
UR  - https://doi.org/10.11648/j.am.20211004.14
AB  - The agricultural and forestry waste pine needle was selected to prepare the biochar which magnetized by the Fe3O4 to treat the typical wastewaters of the dye methylene blue (MB) and carmine (P4R) in view of the problem of quick increasing dye wastewater caused by the rapid development of textile, printing and dyeing industries, and the research result showed the experimental values of the maximum adsorption capacity of modified biochar for MB and P4R were 465.6mg·g-1 and 336.6mg·g-1 respectively. When the dosage of MBC is 0.010g and 0.015g, both the removal rate and the adsorption capacity can be maintained at a high level. Lower pH is conducive to the adsorption of P4R, and a higher pH is conducive to the adsorption of MB. As the adsorption time and initial dye concentration increase, the adsorption capacity of both dyes increases. As the temperature increases, the amount of MB adsorption increases, while the amount of P4R adsorption decreases and the adsorption of MB by MBC is a high-temperature spontaneous adsorption process, and the adsorption of P4R is a low-temperature spontaneous adsorption. The Langmuir model can better describe the adsorption process of MBC to MB, which is a single-layer adsorption, and the Freundlich adsorption model can better describe the adsorption process of MBC to P4R, which is a multi-layer adsorption. The adsorption of MB and P4R by MBC conforms to the quasi-second-order kinetic model.
VL  - 10
IS  - 4
ER  -

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