Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide

Moussa Faye; Antoine Blaise Kama; Mbosse Ndiaye Gueye; Moussa Dieng; Farba Bouyagui Tamboura; Romain Gautier; Mohamed Gaye

doi:doi:10.11648/j.sjc.20221005.14

Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO₃)₂(H₂O) with H₂L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide

Moussa Faye, Antoine Blaise Kama, Mbosse Ndiaye Gueye, Moussa Dieng, Farba Bouyagui Tamboura, Romain Gautier, Mohamed Gaye

Published in Science Journal of Chemistry (Volume 10, Issue 5)

Received: 7 September 2022 Accepted: 20 September 2022 Published: 11 October 2022

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Abstract

Herein we reported the crystal structure of a new coordination polymer formulated as Ce(NO₃)₂(HL)·H₂O obtained by the reaction of N'-[(2-hydroxyphenyl)methylidene]pyridine-3-carbohydrazide (H₂L) and Cerium nitrate hexahydrate in 1:1 ratio in methanol. The ligand and the coordination polymer were firstly characterized by FTIR and physical measurement. Suitable crystals were grown by slow evaporation of methanol solution of the coordination polymer. The title compound crystallizes in the orthorhombic space group P2₁2₁2₁ with the following unit cell parameters: a = 7.8497(1) Å, b = 9.8380(1) Å, c = 22.3471(3) Å, V = 1725.76(4) Å³, Z = 5, R₁ = 0.019 and wR₂ = 0.036. For each Ce³⁺ ion the ligand acts in its monodeprotonated form, in tridentate fashion through one phenolate oxygen atom, one azomethine nitrogen atom and one oxygen atom of a carbonohydrazide moiety. One pyridine nitrogen atom of the ligand remains uncoordinated. Two nitrate anions act in η¹:η²:μ– mode, one nitrate anion acts in bidentate fashion to each Ce³⁺ while one water molecule complete the coordination around Ce³⁺. The structure, solved by single crystal X–ray diffraction, is a polymer in which the units Ce(NO₃)₂(HL)·H₂O are bridged together by two nitrate anions acting in η¹:η²:μ– mode. Thus, the cerium cations are ten coordinated and the environments are best described as a distorted bicapped square antiprism. The Ce^III···Ce^III distance is 5.2824(4) Å and the bridging angle Ce—O—Ce is 161.7(1)°. The structure is consolidated by intra and intermolecular hydrogen bond.

Published in	Science Journal of Chemistry (Volume 10, Issue 5)
DOI	10.11648/j.sjc.20221005.14
Page(s)	161-169
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Cerium, Schiff Base, Coordination Polymer, X-Rays, Bicapped Square Antiprism

References

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Moussa Faye, Antoine Blaise Kama, Mbosse Ndiaye Gueye, Moussa Dieng, Farba Bouyagui Tamboura, et al. (2022). Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide. Science Journal of Chemistry, 10(5), 161-169. https://doi.org/10.11648/j.sjc.20221005.14

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Moussa Faye; Antoine Blaise Kama; Mbosse Ndiaye Gueye; Moussa Dieng; Farba Bouyagui Tamboura, et al. Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide. Sci. J. Chem. 2022, 10(5), 161-169. doi: 10.11648/j.sjc.20221005.14

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Moussa Faye, Antoine Blaise Kama, Mbosse Ndiaye Gueye, Moussa Dieng, Farba Bouyagui Tamboura, et al. Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide. Sci J Chem. 2022;10(5):161-169. doi: 10.11648/j.sjc.20221005.14

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@article{10.11648/j.sjc.20221005.14,
  author = {Moussa Faye and Antoine Blaise Kama and Mbosse Ndiaye Gueye and Moussa Dieng and Farba Bouyagui Tamboura and Romain Gautier and Mohamed Gaye},
  title = {Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide},
  journal = {Science Journal of Chemistry},
  volume = {10},
  number = {5},
  pages = {161-169},
  doi = {10.11648/j.sjc.20221005.14},
  url = {https://doi.org/10.11648/j.sjc.20221005.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20221005.14},
  abstract = {Herein we reported the crystal structure of a new coordination polymer formulated as Ce(NO3)2(HL)·H2O obtained by the reaction of N'-[(2-hydroxyphenyl)methylidene]pyridine-3-carbohydrazide (H2L) and Cerium nitrate hexahydrate in 1:1 ratio in methanol. The ligand and the coordination polymer were firstly characterized by FTIR and physical measurement. Suitable crystals were grown by slow evaporation of methanol solution of the coordination polymer. The title compound crystallizes in the orthorhombic space group P212121 with the following unit cell parameters: a = 7.8497(1) Å, b = 9.8380(1) Å, c = 22.3471(3) Å, V = 1725.76(4) Å3, Z = 5, R1 = 0.019 and wR2 = 0.036. For each Ce3+ ion the ligand acts in its monodeprotonated form, in tridentate fashion through one phenolate oxygen atom, one azomethine nitrogen atom and one oxygen atom of a carbonohydrazide moiety. One pyridine nitrogen atom of the ligand remains uncoordinated. Two nitrate anions act in η1:η2:μ– mode, one nitrate anion acts in bidentate fashion to each Ce3+ while one water molecule complete the coordination around Ce3+. The structure, solved by single crystal X–ray diffraction, is a polymer in which the units Ce(NO3)2(HL)·H2O are bridged together by two nitrate anions acting in η1:η2:μ– mode. Thus, the cerium cations are ten coordinated and the environments are best described as a distorted bicapped square antiprism. The CeIII···CeIII distance is 5.2824(4) Å and the bridging angle Ce—O—Ce is 161.7(1)°. The structure is consolidated by intra and intermolecular hydrogen bond.},
 year = {2022}
}

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TY  - JOUR
T1  - Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide
AU  - Moussa Faye
AU  - Antoine Blaise Kama
AU  - Mbosse Ndiaye Gueye
AU  - Moussa Dieng
AU  - Farba Bouyagui Tamboura
AU  - Romain Gautier
AU  - Mohamed Gaye
Y1  - 2022/10/11
PY  - 2022
N1  - https://doi.org/10.11648/j.sjc.20221005.14
DO  - 10.11648/j.sjc.20221005.14
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 161
EP  - 169
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20221005.14
AB  - Herein we reported the crystal structure of a new coordination polymer formulated as Ce(NO3)2(HL)·H2O obtained by the reaction of N'-[(2-hydroxyphenyl)methylidene]pyridine-3-carbohydrazide (H2L) and Cerium nitrate hexahydrate in 1:1 ratio in methanol. The ligand and the coordination polymer were firstly characterized by FTIR and physical measurement. Suitable crystals were grown by slow evaporation of methanol solution of the coordination polymer. The title compound crystallizes in the orthorhombic space group P212121 with the following unit cell parameters: a = 7.8497(1) Å, b = 9.8380(1) Å, c = 22.3471(3) Å, V = 1725.76(4) Å3, Z = 5, R1 = 0.019 and wR2 = 0.036. For each Ce3+ ion the ligand acts in its monodeprotonated form, in tridentate fashion through one phenolate oxygen atom, one azomethine nitrogen atom and one oxygen atom of a carbonohydrazide moiety. One pyridine nitrogen atom of the ligand remains uncoordinated. Two nitrate anions act in η1:η2:μ– mode, one nitrate anion acts in bidentate fashion to each Ce3+ while one water molecule complete the coordination around Ce3+. The structure, solved by single crystal X–ray diffraction, is a polymer in which the units Ce(NO3)2(HL)·H2O are bridged together by two nitrate anions acting in η1:η2:μ– mode. Thus, the cerium cations are ten coordinated and the environments are best described as a distorted bicapped square antiprism. The CeIII···CeIII distance is 5.2824(4) Å and the bridging angle Ce—O—Ce is 161.7(1)°. The structure is consolidated by intra and intermolecular hydrogen bond.
VL  - 10
IS  - 5
ER  -

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Moussa Faye

Department of Chemistry, University Alioune Diop, Bambey, Senegal
Antoine Blaise Kama

Department of Chemistry, University Alioune Diop, Bambey, Senegal
Mbosse Ndiaye Gueye

Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal
Moussa Dieng

Department of Chemistry, University Alioune Diop, Bambey, Senegal
Farba Bouyagui Tamboura

Department of Chemistry, University Alioune Diop, Bambey, Senegal
Romain Gautier

Institute of Materials Jean Rouxel, University of Nantes, Nantes, France
Mohamed Gaye

Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal

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Moussa Faye, Antoine Blaise Kama, Mbosse Ndiaye Gueye, Moussa Dieng, Farba Bouyagui Tamboura, et al. (2022). Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide. Science Journal of Chemistry, 10(5), 161-169. https://doi.org/10.11648/j.sjc.20221005.14

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Moussa Faye; Antoine Blaise Kama; Mbosse Ndiaye Gueye; Moussa Dieng; Farba Bouyagui Tamboura, et al. Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide. Sci. J. Chem. 2022, 10(5), 161-169. doi: 10.11648/j.sjc.20221005.14

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Moussa Faye, Antoine Blaise Kama, Mbosse Ndiaye Gueye, Moussa Dieng, Farba Bouyagui Tamboura, et al. Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide. Sci J Chem. 2022;10(5):161-169. doi: 10.11648/j.sjc.20221005.14

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@article{10.11648/j.sjc.20221005.14,
  author = {Moussa Faye and Antoine Blaise Kama and Mbosse Ndiaye Gueye and Moussa Dieng and Farba Bouyagui Tamboura and Romain Gautier and Mohamed Gaye},
  title = {Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide},
  journal = {Science Journal of Chemistry},
  volume = {10},
  number = {5},
  pages = {161-169},
  doi = {10.11648/j.sjc.20221005.14},
  url = {https://doi.org/10.11648/j.sjc.20221005.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20221005.14},
  abstract = {Herein we reported the crystal structure of a new coordination polymer formulated as Ce(NO3)2(HL)·H2O obtained by the reaction of N'-[(2-hydroxyphenyl)methylidene]pyridine-3-carbohydrazide (H2L) and Cerium nitrate hexahydrate in 1:1 ratio in methanol. The ligand and the coordination polymer were firstly characterized by FTIR and physical measurement. Suitable crystals were grown by slow evaporation of methanol solution of the coordination polymer. The title compound crystallizes in the orthorhombic space group P212121 with the following unit cell parameters: a = 7.8497(1) Å, b = 9.8380(1) Å, c = 22.3471(3) Å, V = 1725.76(4) Å3, Z = 5, R1 = 0.019 and wR2 = 0.036. For each Ce3+ ion the ligand acts in its monodeprotonated form, in tridentate fashion through one phenolate oxygen atom, one azomethine nitrogen atom and one oxygen atom of a carbonohydrazide moiety. One pyridine nitrogen atom of the ligand remains uncoordinated. Two nitrate anions act in η1:η2:μ– mode, one nitrate anion acts in bidentate fashion to each Ce3+ while one water molecule complete the coordination around Ce3+. The structure, solved by single crystal X–ray diffraction, is a polymer in which the units Ce(NO3)2(HL)·H2O are bridged together by two nitrate anions acting in η1:η2:μ– mode. Thus, the cerium cations are ten coordinated and the environments are best described as a distorted bicapped square antiprism. The CeIII···CeIII distance is 5.2824(4) Å and the bridging angle Ce—O—Ce is 161.7(1)°. The structure is consolidated by intra and intermolecular hydrogen bond.},
 year = {2022}
}

Copy | Download

TY  - JOUR
T1  - Synthesis and Characterization of a Coordination Polymer Ce(HL)(NO3)2(H2O) with H2L = N'-[(2-hydroxyphenyl) Methylidene] pyridine-3-Carbohydrazide
AU  - Moussa Faye
AU  - Antoine Blaise Kama
AU  - Mbosse Ndiaye Gueye
AU  - Moussa Dieng
AU  - Farba Bouyagui Tamboura
AU  - Romain Gautier
AU  - Mohamed Gaye
Y1  - 2022/10/11
PY  - 2022
N1  - https://doi.org/10.11648/j.sjc.20221005.14
DO  - 10.11648/j.sjc.20221005.14
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 161
EP  - 169
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20221005.14
AB  - Herein we reported the crystal structure of a new coordination polymer formulated as Ce(NO3)2(HL)·H2O obtained by the reaction of N'-[(2-hydroxyphenyl)methylidene]pyridine-3-carbohydrazide (H2L) and Cerium nitrate hexahydrate in 1:1 ratio in methanol. The ligand and the coordination polymer were firstly characterized by FTIR and physical measurement. Suitable crystals were grown by slow evaporation of methanol solution of the coordination polymer. The title compound crystallizes in the orthorhombic space group P212121 with the following unit cell parameters: a = 7.8497(1) Å, b = 9.8380(1) Å, c = 22.3471(3) Å, V = 1725.76(4) Å3, Z = 5, R1 = 0.019 and wR2 = 0.036. For each Ce3+ ion the ligand acts in its monodeprotonated form, in tridentate fashion through one phenolate oxygen atom, one azomethine nitrogen atom and one oxygen atom of a carbonohydrazide moiety. One pyridine nitrogen atom of the ligand remains uncoordinated. Two nitrate anions act in η1:η2:μ– mode, one nitrate anion acts in bidentate fashion to each Ce3+ while one water molecule complete the coordination around Ce3+. The structure, solved by single crystal X–ray diffraction, is a polymer in which the units Ce(NO3)2(HL)·H2O are bridged together by two nitrate anions acting in η1:η2:μ– mode. Thus, the cerium cations are ten coordinated and the environments are best described as a distorted bicapped square antiprism. The CeIII···CeIII distance is 5.2824(4) Å and the bridging angle Ce—O—Ce is 161.7(1)°. The structure is consolidated by intra and intermolecular hydrogen bond.
VL  - 10
IS  - 5
ER  -

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